1) Each atom in a pure element has an oxidation number of 0
2) Monatomic ions have an oxidation number equal to the charge on the ion
3) Fluorine always has an oxidation number of -1 in compounds with other elements
4) Cl, Br, and I always have an oxidation number of -1 in compounds, except when combined with oxygen or fluorine
5) The oxidation number of H is +1 and 0 is -2 in most compounds
There are exceptions:
in compounds with metals, H is -1
in peroxides, O has a charge of -1
6) The sum of the oxidation numbers for atoms in a neutral compound is 0
(no charge is shown at end)
In a polyatomic ion, the sum must be equal to the ion charge
http://www.drcruzan.com/Images/Chemistry/OxidationNumbers/OxidationNumbersTable.png |
Here are some references to go through the process of figuring them out:
Video: https://www.youtube.com/watch?v=81WdyqvLlVA
Website http://www.occc.edu/kmbailey/chem1115tutorials/oxidation_numbers.htm